| Unlockable: | How to Unlock: |
| Bon Clay | Unlock Hina, then complete "Event Battle" as Usopp |
| Crocodile | Complete "Event Battle" as Robin |
| Enel | Unlock all other characters, then complete "Event Battle" as Luffy |
| Hina | Unlock Enel, then complete "Event Battle" as Usopp on hard |
| Orm | Finish "Event Battle" as Chopper |
| Smoker | Finish "Event Battle" as Zero |
| Wiper | Finish "Event Battle" as Luffy |
